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Nano ZnO/TiO_2 Photo-Catalyst as an Anti-Ultra Violet Agent on Indigofera tinctoria Colored Cotton Fabric

机译:纳米ZnO / TiO_2光催化剂作为Indigofera Tincororia彩色棉织物的抗超紫代理

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The application of Indigofera tinctoria as natural dyes in textile industries has its own limitation. Exposure to sunlight can promote color fading in the fabric because ultra violet (UV) rays contained in the sunlight can damage the chromophore group in dye structure, especially for natural dye which has less stability structure compared to the synthetic dyes. Nano ZnO/TiO_2 photocatalyst is a semiconductor material which has band gap that proportional to the wavelength of UV rays. This property makes this material is suitable for UV absorber. This study aims to improve the resilience of Indigofera tinctoria dye towards UV rays by utilizing nano ZnO/TiO_2 as an additive. Methods of this research include the manufacture of nano ZnO/TiO_2 by sonication method carried out in atmospheric pressure at temperature of 30°C for 30 minutes. The obtained ZnO/TiO_2 nanoparticle was diluted in ethanol and applied on Indigofera tinctoria colored cotton fabric using simple dipping method. The independent variables in this study were variation of ZnO/TiO_2 weight ratio (20, 21 and 22%), time of sonication ZnO/TiO_2 (10, 20 and 30 minutes), and concentration of ZnO/TiO_2 applied on fabric (75, 150, and 300 ppm). ZnO/TiO_2 nanoparticle was characterized using X-Ray Diffraction (XRD) and Scanning Electron Microscopy-Energy Dispersive X-Ray Spectroscopy (SEM-EDX). Evaluation of dye degradation on Indigofera tinctoria dye fabric was done by color strength analysis. The data obtained was analyzed by Response Surface Method (RSM) assisted by minitab18 software. Optimum operation condition were found to be 20% ZnO in ZnO/TiO_2, 30 minutes of sonication, and 300 ppm ZnO/TiO_2. The results from this study showed that nano ZnO/TiO_2 were successfully synthesized and could be a potential candidate as an additive to increase the color stability of the dye.
机译:IndigoferaTictia作为纺织工业中天然染料的应用有自己的限制。暴露于阳光可以促进织物中的颜色褪色,因为阳光中包含的紫外线(UV)光线可能会损坏染料结构中的发色团,特别是对于与合成染料相比具有较少稳定性结构的天然染料。纳米ZnO / TiO_2光催化剂是具有与UV射线波长成比例的带隙的半导体材料。该物业使该材料适用于UV吸收器。本研究旨在通过利用纳米ZnO / TiO_2作为添加剂来改善Indigofera Tinotoria Dye对紫外线的恢复性。该研究的方法包括通过在大气压下在30℃的温度下在30℃下进行30分钟的超声处理方法制造纳米ZnO / TiO_2。将得到的ZnO / TiO_2纳米颗粒在乙醇中稀释,并使用简单的浸渍法在靛蓝酊棉织物上施用。本研究中的独立变量是ZnO / TiO_2重量比(20,21和22%)的变化,超声ZnO / TiO_2(10,20和30分钟),施加在织物上的ZnO / TiO_2的浓度(75, 150和300 ppm)。使用X射线衍射(XRD)和扫描电子显微镜 - 能量分散X射线光谱(SEM-EDX)表征ZnO / TiO_2纳米粒子。用色强度分析对靛蓝酊织物进行染料降解的评价。通过Minitab18软件辅助的响应表面方法(RSM)分析所获得的数据。发现最佳操作条件是ZnO / TiO_2,30分钟超声的20%ZnO,300ppm ZnO / TiO_2。本研究的结果表明,纳米ZnO / TiO_2成功合成,并且可以是潜在的候选剂作为添加剂,以增加染料的颜色稳定性。

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